Publications

Barium-Catalyzed Dehydrocoupling of Terminal Alkynes and Hydrosilanes.
S. Mohan, E. Clot, M. Cordier, J.-F. Carpentier, Y. Sarazin ChemistryEurope, 2026, 4 , 2, e202500401.
DOI : 10.1002/ceur.202500401.

Electroreductive Nickel-Catalyzed Intramolecular Hydrosilylation of Alkenes.
M. Reboli, M.Durandetti ACS Omega, 2026, 11, 10807-10813.
DOI : 10.1021/acsomega.5c13201.

Intramolecular Carbolithiation of Alkynes: Observation, Mechanism, Applications.
J. Maddaluno, C. Fressigné, M.Durandetti Synlett, 2025, ASAP.
DOI : 10.1055/a-2733-1807.

Solvent-dependent electronic dichotomy in zinc complexes with non-innocent ligands: divalent Zn(+II) vs.monovalent Zn(+I) forms. M. Le Roch, A. Perez-Luna, H. Gerard, F. Chemla, S. Halbert. Phys. Chem. Chem. Phys. 2026, 28, 1845–1852. 
DOI : 10.1039/D5CP03669K.

Di-tert-Butyl-Peroxide–CuI Promoted Radical Hydrogermylation of Alkenes. L. Lorenzini, A. Barbero, R. Blieck, F. Ferreira, A. Perez-Luna. European Journal of Organic Chemistry, 2026, e202501041. 
DOI : 10.1002/ejoc.202501041.

Singlet Carbenes Are Stereoinductive Main Group Ambiphiles
Jan Lorkowski, Patrick Yorkgitis, Fanny Morvan, Jennifer Morvan, Nicolas Vanthuyne, Thierry Roisnel, Milan Gembicky, Guy Bertrand, Marc Mauduit, Rodolphe Jazzar
J. Am. Chem. Soc. 2025, 147, 17, 14777–14784
https://doi.org/10.1021/jacs.5c03845

Synthesis of an Ultra-Bright Rotaxane with Threaded BODIPY Stoppers
Matthieu Hicguet, Olivier Mongin, Yann R. Leroux, Fabienne Berrée, Yann Trolez
Org. Lett. 2025, 27, 44, 12217–12222
https://doi.org/10.1021/acs.orglett.5c03492

Photoinduced Deprotection of 2-Nitrophenylneopentyl Glycol Boronates Enables Light-Triggered Polycondensation of Siloxanes
Dr. Marion Boyet, Dr. Boris Colin, Dr. Guillaume Michaud, Prof. Emilie Genin, Dr. Sandra Pinet, Dr. Laurent Chabaud, Dr. Mathieu Pucheault
Chemistry A European J 2025, 31 (6), e202404577
https://doi.org/10.1002/chem.202404577

Lewis Acid-Catalyzed Tandem Cyclizations of 1,2-Diarylalkenols
Arnaud Espied, Djamila Azrou, Régis Guillot, Aurélien Alix, Vincent Gandon, Christophe Bour
Adv. Synth. Catal. 2025, 367 (17), e70065
https://doi.org/10.1002/adsc.70065

Continuous Flow Synthesis of α-Chloroketones from Esters
Léna Brassart, Maxime Manneveau, Thomas Poisson, Julien Legros, Philippe Huez, Massimiliano Forcato, Philippe Jubault, Laëtitia Chausset-Boissarie
Adv. Synth. Catal. 2025, 367 (10), e202401438
https://doi.org/10.1002/adsc.202401438

Synthesis of non-symmetric ortho-functionalized azoarenes through arylation of arylazo sulfones
Rayhane Hammami, Victor Flon, Morgane Sanselme, Julien Legros, Isabelle Chataigner and Laëtitia Chausset-Boissarie 
Org. Chem. Front., 2025, 12, 6953-6960
https://doi.org/10.1039/D5QO00932D

Investigation of arene and heteroarene nitration supported by high-throughput experimentation and machine learning
Taline Kerackian, Clément Wespiser, Matthieu Daniel, Eric Pasquinet and Eugénie Romero  
Digital Discovery, 2025, 4, 1662-1671
https://doi.org/10.1039/D5DD00086F

Hexafluoroisopropanol-Promoted Substitution Toward the Synthesis of Enantiopure Ferrocene Phosphines
Sirine Boussandel, William Erb, Thierry Roisnel, Marielle Blot, Jean-Pierre Hurvois, Ian Butler, Ali Samarat, Florence Mongin
Synthesis 2025; 57(21): 3211-3226
https://doi.org/10.1055/a-2640-7616

Robust C3-Symmetric Aluminate Hydride for CO₂ Hydroboration Catalysis: Mechanistic Insights and Countercation Influence on Catalytic Performance
Sokolovicz, Y. C. A.; Hild, F.; Tongdee, S.; Gourlaouen, C.; dos Santos, J. H. Z.; Schrekker, H. S.; Dagorne, S. A.
Inorg. Chem. 2025, 64 (4), 2096–2105.
https://doi.org/10.1021/acs.inorgchem.4c05070.

Stable Mg²⁺ Dication Weakly Stabilized/Coordinated in Solution: Synthesis, Structure, Reactivity, and Use in Catalysis
Xu, X.; Chaumont, A.; Gourlaouen, C.; Tongdee, S.; Munshi, S.; Jacques, B.; Wehmschulte, R.; Dagorne, S.
Angew Chem Int Ed 2025, 64 (26), e202506266.
https://doi.org/10.1002/anie.202506266.

Ca²⁺ Stabilized by Carborate Anions: Synthesis, Structure, and Reactivity
Munshi, S.; Gupta, G.; Gourlaouen, C.; Dagorne, S.; Wehmschulte, R. J.
Chemistry A European J 2025, 31 (41), e202501763
https://doi.org/10.1002/chem.202501763

New Aluminum Complexes with an Asymmetric Amidine–Imine Ligand: Synthesis, Characterization, and Application in Catalysis
Gómez Zamorano Fernando, María José Rojas, Sonia Mallet-Ladeira, Alan R. Cabrera, Jordan Garo, Jean-Marc Sotiropoulos, Eddy Maerten, David Madec, and René S. Rojas.
Molecules, 2025, 30, no. 19: 3842.
https://doi.org/10.3390/molecules30193842

Tetra- and penta-coordinated aluminum complexes with bis-amidine ligands and their reactivity for efficient CO₂ transformation to cyclic carbonates
Alejandra Acuña, Nery Villegas-Escobar, Fernando Gómez Zamorano, Nicole Keim-Gyllen, Sonia Mallet-Ladeira, Eddy Maerten, David Madec* and René S. Rojas*
Dalton Trans., 2025, 54, 17180-17188
https://doi.org/10.1039/D5DT02221E

A Reactivity Study of Well-Defined Alkenylalanes Toward Anions, Lewis-Bases and Benzophenone
Alejandra Acuña, Akshitha Selvaraj, Marie Cordier, Thierry Roisnel, Daniel Müller, Gilles Alcaraz, Marc Devillard*
Inorg. Chem., 2025, 64, 20963−20976
https://doi.org/10.1021/acs.inorgchem.5c02978

E-Selective Alkenyl Chloride Synthesis via In(III)- and Fe(III)-Mediated Activation of Tertiary Chlorides and Alcohols
Paul Charki, Daniel S. Müller*
ChemistrySelect, 2025, 10, e03325
https://doi.org/10.1002/slct.202503325

Reactions of Tertiary Aliphatic Cations with Silylated Alkynes: Substitution, Cyclization and Unexpected C−H Activation Products
Paul Charki, Marie Cordier, Prof. Dr. Kai E. O. Ylijoki*, Daniel S. Müller*
Chem. Eur. J., 2025, 31, e202403979
https://doi.org/10.1002/chem.202403979

FAlen-Zn Complexes for the Cycloaddition of CO₂ to Epoxide and the Ring-Opening Polymerization of Lactide
Thu-Van Nguyen, Benjamin Théron, Lukáš Vlk, Valentin Vaillant-Coindard, Cédric Balan, Jérôme Bayardon, Laurent Plasseraud, Yoann Rousselin, Paul Fleurat-Lessard,* Raluca Malacea-Kabbara*, Pierre Le Gendre*
ACS Catalysis, 2025, 15, 14087-14099.
https://doi.org/10.1021/acscatal.5c03972

Synthesis of N,N-dimethylaminoethyl acrylate via a zinc phenoxyimine and phenoxyamidine complexes catalyzed transesterification reaction
Quentin Gaydon, Raluca Malacea-Kabbara, Jérôme Bayardon, Laurent Plasseraud, Michel Picquet, Pierre Le Gendre*, Benoit Legras, Johann Kieffer
Applied Organometallic Chemistry, 2025, 39, e70387.
https://doi.org/10.1002/aoc.70387

Benzo[c]cinnolinium trifluoromethanesulfonate architectures induced by organotin(IV) complex
Hélène Cattey* and Laurent Plasseraud*
Crystals, 2025, 15, 655.
https://doi.org/10.3390/cryst15070655

Isolation and Characterization of {[n-Bu₂Sn(OH₂)(Phen)(O₃SCF₃)][CF₃SO₃] (Phen = 1,10-phenanthroline): The missing link
Hélène Cattey, Marie-José Penouilh, Quentin Bonnin, Laurent Plasseraud*
Journal of Organometallic Chemistry, 2025, 1027, 123511.
https://doi.org/10.1016/j.jorganchem.2025.123511

Solvated Alkali and Calcium 2,2,6,6‐Tetramethylpiperidides: Synthesis and Reactivity
Duneş, G.; Bastien, C.; Anandaraj, S. J. L.; Cordier, M.; Dorcet, V.; Roisnel, T.; Erb, W.; Mongin, F.; Sarazin, Y.
Eur. J. Inorg. Chem., 2025, 28, e202500451 (10 p.)
https://doi.org/10.1002/ejic.202500451

Synthesis of an Ultra-Bright Rotaxane with Threaded BODIPY Stoppers
Hicguet, M.; Mongin, O.; Leroux, Y. R.; Berrée, F.; Trolez, Y.
Org. Lett. 2025, 27, 44, 12217–12222
https://doi.org/10.1021/acs.orglett.5c03492

Photoinduced Reduction and Deuteration of Aryl Halides with NHC-Boranes
Lalande, G.; Pinet, S. ; Robert, F.; Chabaud, L.; Pucheault, M.
Eur. J. Org. Chem. 2025, e202500543
https://doi.org/10.1002/ejoc.202500543

Self-Healing and Creep-Resistant Injectable Hydrogel from Aminoborinate Chemistry and Phase Separation
Sun, H.; Göde, I.; Bonnard, M.; Liautard, V.; Pomes-Hadda, M.; Aime, S.; Chabaud, L.; Edera, P.; Guérinot, A.; Pucheault, M.; Nicolaÿ, R.
ACS Materials Lett. 2025, 7, 7, 2534–2540
https://doi.org/10.1021/acsmaterialslett.5c00532

A Comprehensive Review of Intramolecular Hydrosilylation of Alkynes and Alkenes
Reboli, M.; Durandetti, M.
ChemCatChem, 2025, e202402136
https://doi.org/10.1002/cctc.202402136

Double addition of organoaluminum reagents onto nitriles to access diethynyl carbinamines
Nguyen, H. G.;Boeda, F.; Bertus, P.; Pearson-Long, M. S. M.
Org. Biomol. Chem. 2025, 23, 7697–7701
https://doi.org/10.1039/D5OB00911A

An Overview of the Direct Preparation of Organoaluminum Compounds
Piccardi, R.; Micouin, L.
Synthesis 2025, 57, 3105-3126
https://doi.org/10.1055/a-2669-5996

1.03 – Organoaluminum Reagents
Micouin, L.; Piccardi, R.
Comprehensive Organic Synthesis (Third Edition) Volume 1, 2025, Pages 45-69
https://doi.org/10.1016/B978-0-323-96025-0.00041-7

Catalytic silylation of alkynyl C(sp)–H bonds with tert-butyl-substituted silyldiazenes
Zeng, Y.; Fensterbank, L.; Chauvier, C.
ChemCatChem, 2025, 17, e202500121
https://doi.org/10.1002/cctc.202500121

Catalytic alkoxysilylation of C-H bonds with tert-butyl-substituted alkoxysilyldiazenes
Saadi, L.; Valade, L.; Chauvier, C.
Chem. Sci., 2025, 16, 9794–9801
https://doi.org/10.1039/D5SC02059J

Ansa-effects in alkaline earth metal octaphenylmetallocenophanes and a derived ansa-ferrocene
Shephard, A. C. G.; Bouammali, A.; Delon, A.; Guo, Z.; Chevreux, S.; Niebel, C.; Dautel, O.; Simler, T.; Deacon, G. B.; Junk, P. C.;* Jaroschik, F.*  
Dalton Trans., 2025, 54, 13918-13928
https://doi.org/10.1039/D5DT01881A

Investigating di-n-Butylcalcium
Dunes, G.; Hédouin, M.; Bastien, C.; Kahlal, S.; Cordier, M.; Erb, W.; Mongin, F.; Saillard, J.-Y.; Oulyadi, H.;* Sarazin, Y.*
ChemistryEurope, 2025, 3, e202500196 (16 p.)
https://doi.org/10.1002/ceur.202500196
HAL: hal-05210274

Mannich Reaction of Secondary Benzylzinc Reagents: Synthesis of α,β-Disubstituted β-Arylethylamines
Leroux, B.: Banchini, F.; Jackowski, O.; Perez-Luna, A.; Chemla, F.; Presset, M.; Le Gall, E. Asian J. Org. Chem. 2025, 14, e202500091
https://doi.org/10.1002/ajoc.202500091

Phosphorus-containing polycarbosilazanes: Synthesis via dehydrocoupling catalysis and flame-retardant properties
A. Soran, P. M. Chapple, C. Longuet, R. Sonnier,* M. Cordier, J.-F. Carpentier,* Y. Sarazin*
Dalton Trans. 2025, 54, 2037-2054
https://doi.org/10.1039/D4DT03172E

Of perfluorinated aryllead(II) complexes
A.-A. Someșan,* T. Roisnel, Y. Sarazin*
Dalton Trans., 2025, 54, 482-486
https://doi.org/10.1039/D4DT03167A